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dc.contributor.authorCaetano, Miguel-
dc.contributor.authorSantos, Margarida M. Correia dos-
dc.contributor.authorRosa, Nuno; Carvalho, Ines-
dc.contributor.authorRodriguez, Jose German-
dc.contributor.authorBelzunce, Maria Jesus-
dc.contributor.authorMenchaca, Iratxe-
dc.contributor.authorLarreta, Joana-
dc.contributor.authorSanz, Marta Rodrigo; Millan-Gabet, Vanessa-
dc.contributor.authorGonzalez, Jean-Louis-
dc.contributor.authorAmouroux, Isabelle-
dc.contributor.authorGuesdon, Stephane-
dc.contributor.authorMenet-Nedelec, Florence-
dc.contributor.authorWhite, Blanaid-
dc.contributor.authorRegan, Fiona-
dc.contributor.authorNolan, Martin-
dc.contributor.authorMcHugh, Brendan; Bersuder, Philippe-
dc.contributor.authorBolam, Thi-
dc.contributor.authorRobinson, Craig D.-
dc.contributor.authorFones, Gary R.-
dc.contributor.authorZhang, Hao-
dc.contributor.authorSchintu, Marco-
dc.contributor.authorMontero, Natalia-
dc.contributor.authorMarras, Barbara-
dc.date.accessioned2023-10-04T10:45:11Z-
dc.date.available2023-10-04T10:45:11Z-
dc.date.issued2022-
dc.identifierWOS:000802997300003-
dc.identifier.issn0025-326X-
dc.identifier.urihttp://dspace.azti.es/handle/24689/1648-
dc.description.abstractThis study investigates the relationships among Ni, Cd and Pb's different chemical forms determined by different methodologies in coastal and transitional waters across a broad geographical scale. Concentrations were measured in spot samples and through passive sampling (DGT). High variability of metal concentrations was found among sampling sites and methodologies due to natural water fluctuations rather than to a given metal or method. Total dissolved metal concentrations in spot samples were lower than the EQS-WFD values. The labile fractions of Cd and Pb, measured in spot samples by Anodic Stripping Voltammetry and by DGT-ICPMS, were highly correlated. Similar labilities were found for Cd, while for Pb, the ASV labile fraction was asymptotic to 50\% lower. These results reflect the pool of mobile and labile species available towards each technique kinetic window, and they seem not to be affected by discrete sampling flaws.-
dc.language.isoEnglish-
dc.publisherPERGAMON-ELSEVIER SCIENCE LTD-
dc.subjectPriority metals-
dc.subjectBroad geographical scale-
dc.subjectEuropean coastal and transitional waters-
dc.subjectDGT-
dc.subjectVoltammetry-
dc.subjectDISSOLVED TRACE-METALS-
dc.subjectSPECIATION ANALYSIS-
dc.subjectSURFACE WATERS-
dc.subjectNATURAL-WATERS-
dc.subjectMARINE WATERS-
dc.subjectFULVIC-ACID-
dc.subjectCU-
dc.subjectCD-
dc.subjectNI-
dc.subjectPB-
dc.titleMetals concentrations in transitional and coastal waters by ICPMS and voltammetry analysis of spot samples and passive samplers (DGT)-
dc.typeArticle-
dc.identifier.journalMARINE POLLUTION BULLETIN-
dc.format.volume179-
dc.contributor.funderInterreg Atlantic Area Trans-national Cooperation Programme [UIDB/00100/2020, UIDP/00100/2020, UID/QUI/00100/2019]-
dc.contributor.funderMONITOOL project - Interreg Atlantic Area Transnational Cooperation Programme-
dc.contributor.funderAgencia Portuguesa do Ambiente (Portugal)-
dc.contributor.funderURA Agencia Vasca del Agua (Spain)-
dc.contributor.funderConsejo Insular de Aguas de Gran Canaria (Spain)-
dc.contributor.funderViceconsejeria Medioambiente del Gobierno de Canarias (Spain)-
dc.contributor.funderAgence Francaise pour la Biodiversite (France)-
dc.contributor.funderForas na Mara-Marine Environment and Food Safety Services (Ireland)-
dc.contributor.funderEnvironmental Protection Agency (Ireland)-
dc.contributor.funderScottish Government-Marine Scotland (United Kingdom)-
dc.contributor.funderScottish Environment Protection Agency (United Kingdom)-
dc.contributor.funderCQE-IST [UIDB/00100/2020, UIDP/00100/2020, UID/QUI/00100/2019]-
dc.contributor.funder[UID/QUI/00100/2013]-
dc.contributor.funderFundação para a Ciência e a Tecnologia [UID/QUI/00100/2019] Funding Source: FCT-
dc.identifier.e-issn1879-3363-
dc.identifier.doi10.1016/j.marpolbul.2022.113715-
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